Low-Temperature Fabrication of Mesoporous Titanium Dioxide Thin Films with Tunable Refractive Indices for One-Dimensional Photonic Crystals and Sensors on Rigid and Flexible Substrates

Li, C. and Colella, N. S. and Watkins, J. J.. (2015) Low-Temperature Fabrication of Mesoporous Titanium Dioxide Thin Films with Tunable Refractive Indices for One-Dimensional Photonic Crystals and Sensors on Rigid and Flexible Substrates. Acs Applied Materials & Interfaces, 7 (24). pp. 13180-13188.

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Abstract

Highly transparent mesoporous titanium dioxide (TiO2; anatase), thin films were prepared at room temperature via ultraviolet (UV) irradiation Of hybrid polymer-TiO2 nanoparticle thin films: This approach utilized a UV-curable polymer in conjunction with the photocatalytic activity of TiO2 to form and degrade the organic component of the composite films in one step, producing films with well-controlled porosity and refractive index. By adjustment of the loading of TiO2 nanoparticles in the host polymer, the refractive index was tuned between 1.53 and 1.73. Facile control of these properties and mild processing conditions was leveraged to fabricate robust one-dimensional photonic crystals (Bragg mirrors) consisting entirely of TiO2 on silicon and flexible poly(ethylene terephthalate) substrates. The mesoporous Bragg mirrors were shown to be effective chemical vapor sensors with strong optical responses.

Item Type: Article
Additional Information: ISI Document Delivery No.: CL6FOTimes Cited: 0Cited Reference Count: 52Li, Cheng Colella, Nicholas S. Watkins, James J.NSF Center for Hierarchical Manufacturing CMMI-1025020; G8 Research Councils Initiative on Multilateral Research through the NSF CMMI-1258336Funding from the NSF Center for Hierarchical Manufacturing (Grant CMMI-1025020) and G8 Research Councils Initiative on Multilateral Research through the NSF (Grant CMMI-1258336) is gratefully acknowledged. We thank Irene Howell for assistance with the COMSOL Multiphysics simulation software.0Amer chemical socWashington
Uncontrolled Keywords: Materials Science
Collections: Nanomanufacturing Research Collection > Nanomanufacturing Nanoscale Science and Engineering Centers > Center for Hierarchical Manufacturing
Depositing User: Robert Stevens
Date Deposited: 12 Nov 2015 18:38
Last Modified: 12 Nov 2015 18:38
URI: http://eprints.internano.org/id/eprint/2317

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