Controlled integration of oligo- and polythiophenes at the molecular scale

Colella, N. S. and Zhang, L. and McCarthy-Ward, T. and Mannsfeld, S. C. B. and Winter, H. H. and Heeney, M. and Watkins, J. J. and Briseno, A. L.. (2015) Controlled integration of oligo- and polythiophenes at the molecular scale. Physical Chemistry Chemical Physics, 17 (40). pp. 26525-26529.

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Abstract

High molecular weight PBTTT-C-12 is blended with the pure trimer, BTTT-3, to enhance intergrain connectivity and charge transport. Analysis of the morphology and crystallinity of the blends shows that the polymer and oligomer are well-integrated, leading to high hole mobilities, greater than 0.1 cm(2) V-1 s(-1), in films that contain as much as 83% oligomer.

Item Type: Article
Additional Information: ISI Document Delivery No.: CT3AXTimes Cited: 0Cited Reference Count: 19Colella, Nicholas S. Zhang, Lei McCarthy-Ward, Thomas Mannsfeld, Stefan C. B. Winter, H. Henning Heeney, Martin Watkins, James J. Briseno, Alejandro L.National Science Foundation DMR-1112455, CMMI 1334460; Center for Hierarchical Manufacturing CMMI-0531171; Engineering and Physical Sciences Research Council EP/G060738/1; German Research Foundation (DFG) within the Cluster of Excellence 'Center for Advancing Electronics Dresden'We thank the National Science Foundation (DMR-1112455), the Center for Hierarchical Manufacturing (CMMI-0531171), and the Engineering and Physical Sciences Research Council (EP/G060738/1) for support of this work. H. H. W. acknowledges the National Science Foundation (CMMI 1334460). The authors thank Edmund Kingsland Burnett for his assistance in acquiring the GIWAXS data, as well as Dr Anna Warren and Dr Sean Parkin for their work in determining the unit cell parameters of BTTT-3. S.C.B.M. acknowledges support by the German Research Foundation (DFG) within the Cluster of Excellence 'Center for Advancing Electronics Dresden'.0Royal soc chemistryCambridge1463-9084
Uncontrolled Keywords: Physics
Collections: Nanomanufacturing Research Collection > Nanomanufacturing Nanoscale Science and Engineering Centers > Center for Hierarchical Manufacturing
Depositing User: Robert Stevens
Date Deposited: 12 Nov 2015 18:38
Last Modified: 12 Nov 2015 18:38
URI: http://eprints.internano.org/id/eprint/2345

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