Shear Distortion and Failure of Capillary Bridges. Wetting Information Beyond Contact Angle Analysis

Wang, L. M. and McCarthy, T. J.. (2013) Shear Distortion and Failure of Capillary Bridges. Wetting Information Beyond Contact Angle Analysis. Langmuir, 29 (25). pp. 7776-7781.

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Abstract

Water capillary bridges are prepared that span hydrophilic pinning features on parallel opposing smooth, flat, and hydrophobic surfaces. These bridges are distorted by shearing the parallel plates at a low rate. The capillary bridges lengthen and distort to balance Laplace pressure (equilibrate mean curvature) as the features are separated and eventually rupture at a distance that is a function of the liquid volume, the advancing and receding contact angles of the surfaces, the separation between the parallel surfaces, and in particular, the shape and orientation of the hydrophilic pinning features. Two modes of capillary bridge failure are observed: (1) tensile, in which the capillary bridge breaks to form sessile drops on both the upper and lower surfaces, and (2) sessile, in which sessile capillary bridge rupture occurs on one surface to form a puddle (contact-line-distorted sessile drop) on the feature and a retained capillary bridge spanning the hydrophobic surface and the hydrophilic feature on the opposing surface. The shape and orientation of the features control the mode of capillary bridge failure as well as the distribution of water between the two separate sessile drops or the retained capillary bridge and the puddle.

Item Type: Article
Additional Information: ISI Document Delivery No.: 173QNTimes Cited: 0Cited Reference Count: 12Wang, Liming McCarthy, Thomas J.Materials Research Science and Engineering Center at the University of Massachusetts DMR-0820506; Center for Hierarchical Manufacturing at the University of Massachusetts CMMI-1025020We thank Henkel and Gelest for support as well as the Materials Research Science and Engineering Center (DMR-0820506) and the Center for Hierarchical Manufacturing (CMMI-1025020) at the University of Massachusetts.Amer chemical socWashington
Uncontrolled Keywords: adhesion
Collections: Nanomanufacturing Research Collection > Nanomanufacturing Nanoscale Science and Engineering Centers > Center for Hierarchical Manufacturing
Depositing User: Robert Stevens
Date Deposited: 27 Mar 2014
Last Modified: 27 Mar 2014 20:21
URI: http://eprints.internano.org/id/eprint/2183

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